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Anti-Aging — Copper Tripeptide✓ FDA Approved

GHK-Cu

Also known as: Copper peptide GHK · GHK Copper · Glycyl-L-histidyl-L-lysine copper

MW

403.93 Da

Amino Acids

3 AA

Half-Life

2-4 hours

Route

SubQ, Topical

CAS

49557-75-7

Formula

C14H24CuN6O4

Amino Acid Sequence

Gly-His-Lys:Cu2+

Mechanism of Action

GHK-Cu (Glycyl-L-Histidyl-L-Lysine Copper) is a naturally occurring tripeptide-copper complex found in human plasma, saliva, and urine. Plasma levels decline from ~200 ng/mL at age 20 to ~80 ng/mL by age 60.

COLLAGEN SYNTHESIS: Stimulates collagen I and III production via TGF-β pathway activation in fibroblasts. Promotes decorin synthesis (collagen fiber organization). This is the primary mechanism for skin rejuvenation and wound healing.

ECM REMODELING: Activates matrix metalloproteinases (MMPs) for controlled breakdown of damaged ECM, while simultaneously promoting synthesis of replacement collagen, elastin, and glycosaminoglycans. This remodeling (not just new collagen) distinguishes GHK-Cu from simple collagen stimulators.

ANTIOXIDANT: Copper delivery activates superoxide dismutase (SOD) — a key antioxidant enzyme. Reduces lipid peroxidation and iron-catalyzed oxidative damage.

ANTI-INFLAMMATORY: Suppresses NF-κB → reduces TNF-α, IL-6. Reduces TGF-β-induced scar formation (anti-fibrotic in context of wound healing, preventing excessive scarring).

GENE EXPRESSION: Genome-wide studies show GHK-Cu modulates expression of 4,000+ genes — 59% of genes altered by GHK return expression toward a "younger" pattern. Upregulates DNA repair genes and downregulates inflammatory genes.

HAIR: Enlarges hair follicles (vellus → terminal conversion), extends anagen phase, and increases follicle blood supply via VEGF.

NERVE REGENERATION: NGF-like signaling promotes Schwann cell migration and nerve fiber growth.

Dosing Protocol

Low Dose

███ – ███ mcg/day

Standard Dose

███ mcg/day

High Dose

███ – ███ mcg/day

Dosing protocols are for paid members

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Frequency

Topical: daily AM and/or PM.

Half-Life

2-4 hours

Reconstitution Guide

Full reconstitution protocol with BAC water volumes, concentration math, and units-to-draw per dose is available on the Clinical plan.

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Clinical Warnings

Copper accumulation risk with chronic high-dose use.

Not for use near active cancers (growth factor stimulation).

Injectable route poorly characterized.

Hyperpigmentation at injection sites reported anecdotally.

Copper toxicity possible with excessive injectable use.

Contraindications

Absolute

Wilson disease

Copper hypersensitivity

Pregnancy

Relative Cautions

Copper metabolism disorders

Liver disease

Side Effect Profile

Mild

  • Skin irritation (topical)
  • Injection site redness

Moderate

  • Mild nausea
  • Headache

Synergistic Peptides

BPC-157TB-500Epithalon

Common Stacks

BPC-157

TB-500

Research Status

MODERATE TOPICAL DATA. Gene expression studies show 4,000+ gene modulation. Wound healing trials positive. Pickart research program (primary). No large injectable RCTs. Topical evidence strongest for skin aging and wound healing.

Frequently Asked Questions

How does GHK-Cu work?

GHK-Cu (Glycyl-L-Histidyl-L-Lysine Copper) is a naturally occurring tripeptide-copper complex found in human plasma, saliva, and urine. Plasma levels decline from ~200 ng/mL at age 20 to ~80 ng/mL by age 60. COLLAGEN SYNTHESIS: Stimulates collagen I and III production via TGF-β pathway activation in fibroblasts. Promotes decorin synthesis (collagen fiber organization). This is the primary mechanism for skin rejuvenation and wound healing. ECM REMODELING: Activates matrix metalloproteinases (MM

What is the standard dose of GHK-Cu?

GHK-Cu dosing protocols are available with a ClinPep Clinical subscription. Dosing varies by indication and patient factors — consult a licensed healthcare provider. General frequency: Topical: daily AM and/or PM.

What is the half-life of GHK-Cu?

The half-life of GHK-Cu is 2-4 hours. This determines optimal dosing frequency and timing.

Who should not use GHK-Cu?

GHK-Cu is absolutely contraindicated in: Wilson disease; Copper hypersensitivity; Pregnancy. Use with caution in: Copper metabolism disorders; Liver disease.

What are the side effects of GHK-Cu?

Common mild side effects include: Skin irritation (topical), Injection site redness. Moderate effects: Mild nausea, Headache.

What peptides stack well with GHK-Cu?

GHK-Cu is commonly stacked with: BPC-157, TB-500, Epithalon.

How do you reconstitute GHK-Cu?

GHK-Cu is reconstituted with bacteriostatic water. Exact volumes, concentrations, and units-to-draw calculations are available in the ClinPep Clinical plan. Always follow your compounding pharmacy's instructions.

How long should you cycle GHK-Cu?

GHK-Cu cycle protocols vary by indication. Detailed cycle length, on/off schedules, and monitoring guidelines are available with ClinPep Clinical access. Consult your healthcare provider for personalized cycling guidance.

References & Citations

10 PubMed studies · 2 clinical trials

An injectable hydroxyapatite microsphere filler loaded with GHK-Cu tripeptide for anti-Inflammatory and antioxidant.

Hu Die, Zhang Xuexun, Gong Shiwen, Ma Wentao et al.. Colloids and surfaces. B, Biointerfaces. 2025

PubMed: 40716276DOI ↗C — Research Article

With the wide application of soft tissue fillers, implant material-induced inflammatory reactions have become a key factor affecting the therapeutic efficacy. This study developed an injectable filler

Copper Complexes with New Glycyl-l-histidyl-l-lysine-Hyaluronan Conjugates Show Antioxidant Properties and Osteogenic and Angiogenic Synergistic Effects.

Greco Valentina, Lanza Valeria, Tomasello Barbara, Naletova Irina et al.. Bioconjugate chemistry. 2025

PubMed: 40123442DOI ↗C — Research Article

In recent years, hyaluronic acid (HA) and the natural tripeptide glycyl-l-histidyl-l-lysine (GHK), especially its copper(II) complex (GHK-Cu), individually have been shown to exert helpful properties

Food-Derived Tripeptide-Copper Self-Healing Hydrogel for Infected Wound Healing.

Chen Han, Yang Pu, Xue Ping, Li Songjie et al.. Biomaterials research. 2025

PubMed: 39902373DOI ↗C — Research Article

The field of infected wound management continues to face challenges, and traditional methods used to cope with wounds include debridement, gauze coverage, medication, and others. Currently, synthetic

Are We Ready to Measure Skin Permeation of Modern Antiaging GHK-Cu Tripeptide Encapsulated in Liposomes?

Ogórek Karolina, Nowak Kinga, Wadych Emilia, Ruzik Lena et al.. Molecules (Basel, Switzerland). 2025

PubMed: 39795193DOI ↗C — Research Article

Cosmetically active compounds (CACs), both of lipophilic and hydrophilic origin, have difficulty reaching the deeper layers of the skin, and this shortcoming significantly reduces their efficacy. One

Palmitoyl copper peptide and acetyl tyrosine complex enhances melanin production in both A375 and B16 cell lines.

Hong Minhua, Gui Yingyue, Xu Jiayao, Zhao Xianglong et al.. Biochemical and biophysical research communications. 2025

PubMed: 39632290DOI ↗C — Research Article

Copper peptide, a low molecular weight peptide composed of glycyl-L-histidyl-l-lysine-copper, possesses anti-aging, anti-inflammatory, and wound healing properties. In this study, we investigated the

Novel Applications of CE-ICP-MS/MS: Monitoring of Antiaging GHK-Cu Cosmetic Component Encapsulation in Liposomes.

Zajda Joanna, Wadych Emilia, Ogórek Karolina, Drozd Marcin et al.. Electrophoresis. 2024

PubMed: 39451062DOI ↗C — Research Article

The hyphenation of the separation technique with the high-sensitive mass spectrometry detection is one of the driving forces of modern analysis enabling measurements in complex matrices. In particular

The glycyl-l-histidyl-l-lysine-Cu2+ tripeptide complex attenuates lung inflammation and fibrosis in silicosis by targeting peroxiredoxin 6.

Bian Yiding, Deng Mingming, Liu Jia, Li Jiaye et al.. Redox biology. 2024

PubMed: 38879894DOI ↗C — Research Article

Silicosis is the most common type of pneumoconiosis, having a high incidence in workers chronically exposed to crystalline silica (CS). No specific medication exists for this condition. GHK, a tripept

Glycyl-l-histidyl-l-lysine prevents copper- and zinc-induced protein aggregation and central nervous system cell death in vitro.

Min Jin-Hong, Sarlus Heela, Harris Robert A. Metallomics : integrated biometal science. 2024

PubMed: 38599632DOI ↗C — Research Article

Common features of neurodegenerative diseases are oxidative and inflammatory imbalances as well as the misfolding of proteins. An excess of free metal ions can be pathological and contribute to cell d

Registered Clinical Trials

Trial Assessing the Impact on Facial Skin Quality, Hydration, and Skin Barrier of Three (3) Hydrafacial Treatments in Adults of All Skin Types.

NCT05932732COMPLETEDPHASE4

Topical GHK-Cu Gel for Acute Skin Wound Healing

NCT07437586RECRUITINGPHASE2

Symptom Indications

Skin agingPoor wound healingHair thinningScarringInflammationCOPD

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This information is for educational and research reference purposes only. ClinPep does not provide medical advice, diagnosis, or treatment recommendations. All protocols should be reviewed by a licensed healthcare provider.